How MTA-STS is deployed
MTA-STS (RFC 8461) has two parts: a TXT record at _mta-sts.yourdomain whose id tells senders when the policy changed, and a policy file at https://mta-sts.yourdomain/.well-known/mta-sts.txt that lists the MX hosts allowed to receive your mail. Senders that support it, Gmail and Microsoft 365 among them, cache the policy for max_age seconds and, in enforce mode, deliver only over TLS with a valid certificate to a listed host. TLS-RPT (RFC 8460) adds daily reports of the TLS connections senders made to you and the failures they met. Check the result with the MTA-STS checker.
Testing first, then enforce
Publish the policy in mode: testing with a TLS-RPT address and read the reports for a week or two. In testing mode nothing changes for delivery; the reports show which senders could not set up valid TLS to your MX hosts. When they are clean, switch to mode: enforce and change the id. Change the id whenever you edit the policy, and add new MX hosts to it before you switch MX records.